Great videos! I wish there was a set of tutorials included for Photoshop CS6 like the Dreamweaver CS6 tutorials that were very enlightening.
The only thing I didn't like was that it wasn't clear enough as to what ORDER to watch the videos in. They should have simply been put in the right order from the moment I went to download them. Also, referring to the proposed order of watching:
1. Web Design 1 - 225min
2. Dreamweaver CS3 + CS4 - 475min
3. CSS Layouts - 89min
4. CSS Lists - 85min
5. Photoshop for the Web - 300min
6. HTML Forms - 45min
7. Horizontal lists with CSS sprites - 24min
8. Beginners Javascript - 300min
9. Beginners PHP - 146min
10. Wordpress Install - 62min

Santo Romano is a quality instructor and is lessons are thorough and easy to follow; I could learn anything form Santo. Tuition by video suits my style of learning and I benefit from the watch and do style.
I have used Photoshop CS3 on and off for a number of years, but I found Beginners CS6 very useful; I recommend it to both beginners and those with some experience of Photoshop.
I am following with CS3 and, while some features are missing, I can still follow and work along with the examples.

It was a nice overview